Page 14 - ScienceFocus (Issue 014)
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Printing. The word itself sounds anything                          polybutadiene. Then, styrene and acrylonitrile
                                                                     are polymerized with polybutadiene. The resultant
but high-tech. Printing documents and/or photos                      polymer is very strong as it combines the strength
has been around for a long time. I? fairly certain                  and rigidity of acrylonitrile and styrene polymers
all of you have used a printer before, at some point                 with the toughness of polybutadiene rubber.
in your life. Sounds pretty boring, eh? But what                     ABS is also a very resistant polymer, being able
if I told you that what you could print would no                     to withstand acid and alkali attacks as well as
longer be limited to two dimensions? What if I told                  mechanical impacts. This, combined with the fact
you that one could print out objects of all kinds, in                that ABS has a relatively high melting point, makes it
different shapes and sizes? Yes, you?e got it: I am                 a favorite material for 3D printers.
talking about 3D printing, a technology hailed as
revolutionary.                                                            Alternatively, you could use PL A plastic in
                                                                     your household printer instead of ABS plastic.
     The principle of 3D printing actually isn? as                  PLA stands for polylactic acid. Due to its name,
complex as you might think. Say you want to print                    people commonly mistake PLA for a polyacid,
a cube. All you have to do is print a regular 2D                     but it is actually a polyester. Since the lactic
square, repeat the process, then stack all the layers                acid monomer contains both a carboxyl group
up together until it becomes a cube. Once you                        (COOH) and a hydroxyl group (OH), PLA is
have enough layers, you can have any shape you                       simply produced by polymerizing lactic acid via
want. Simple. And once you have a basic shape                        condensation. Lactic acid used for PLA production
mastered, you can start moving onto the more                         is usually extracted from sugarcanes or any starch
complex shapes, for example, a sphere, using                         containing substance. As it comes from plants,
the same method. Or a basin, with some hollow                        PLA is considered a bioplastic, and since the ester
internal parts. With 3D printing, almost all shapes                  bonds within the PLA chains can be broken down
can be visualized and crafted. This is achieved by                   enzymatically, it is also a biodegradable plastic,
simple mechanics: all you need is a platform that                    unlike most thermoplastics. In comparison, PLA is
can move in 3 axes: X, Y and Z, and a nozzle gun                     less resistant to mechanical stress than ABS, making
to extrude printing material. But the question now                   it more prone to warping during the 3D print
                                                                     process; this is mostly due to its lower melting point.
                       is, precisely what kind of printing           However, it does produce a smoother surface that
                        material do you use for those                is harder for ABS to achieve. It is also able to print
                                                                     in much finer detail than ABS. So it would be more
                               layers? Surely, regular ink from      precise in molding the desired shape, making PLA
                                     the age-old 2D printers         another favorite for printing materials in 3D printers.
                                     won? work? Guess not.
                                                                          As of now, household 3D printing is mostly used
                                   What are the materials that       to create quick prototypes for assessing their form
                                could best fit the 3D printing       and function. With the use of different printing
                                 purposes? The answer for this       materials, it also helps to rapidly manufacture
                                                                     products on a large industrial scale, especially
                                             lies in chemistry. One  those that require customization. In medicine,
                                             of most common          artificial bones and joints have been 3D-printed
                                          materials used in          for use as prosthetics. Some companies have even
                                      household 3D printers          dared to use 3D printing to construct housing, be it
                                 is acrylonitrile butadiene          for long term use or for temporary refugee housing.
st y rene. Well, what exactly is it? Let? just use its
abbreviation: ABS plastic. You may have already                           To sum up, 3D printing is a unique technology,
encountered ABS before you?e read this article:                     an interdisciplinary force of chemistry and
Lego blocks are in fact ABS plastic. Unlike the                      mechanics. It? quite like using play-doh to mold
(ordinary) polymers you may have learnt in high                      whatever objects you wish, but in a fancier, more
school, ABS plastic is actually made out of not                      precise way. It truly encapsulates the concept of
one, but three monomers, namely 1,3-butadiene,                       bringing abstract ideas to the physical world.
styrene and acrylonitrile. As such, ABS is known
specifically as a terpolymer, with ?er??meaning
three. The terpolymer is made in a series of steps.
First, 1,3-butadiene itself is polymerized, forming
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